图(a)为DZ2(0.05V0Nb)钢900℃淬火的扫描电子显微镜(SEM)下的组织形貌,图(b)(c)(d)(e)为DZ2(0.05V0Nb)钢经900℃淬火后分别在600℃、625℃、650℃、675℃回火1h处理后在扫描电子显微镜(SEM)下的组织形貌,图(f)为能谱图。由图可知,DZ2(0.05V0Nb)钢经淬火后的微观组织为淬火马氏体板条,经不同温度回火后三种钢的微观组织都为回火马氏体板条,且随回火温度的上升,部分马氏体板条发生溶解,回火温度升至675℃时,可以看到马氏体板条明显发生回复。同时,高温回火时有大量的第二相粒子析出,由能谱图(f)可知这些大量弥散的析出相为合金碳化物,回火温度从600℃升至650℃时,合金碳化物析出量明显增多,这可能是因为马氏体在回火过程中发生分解,过饱和的C原子和合金元素从马氏体中脱溶形成碳化物,回火温度的升高,加快了溶质原子扩散速率,从而加快了碳化物析出。图(b)~(e)箭头指向的红色圆圈部分为局部放大图,从中可以更清晰的看出,随回火温度的升高,合金碳化物的形貌从片状变为短棒状,最终在675℃回火时发生球化。
Figure (a) shows the microstructure morphology of DZ2 (0.05V0Nb) steel under scanning electron microscope (SEM) after quenching at 900℃. Figures (b), (c), (d) and (e) show the microstructure morphology of DZ2 (0.05V0Nb) steel after quenching at 900℃ and tempering at 600℃, 625℃, 650℃ and 675℃ for 1h under scanning electron microscope (SEM), and Figure (f) shows the energy spectrum. The figure shows that DZ2 (0.05 V0Nb) steel after quenching microstructure of quenched martensite lath, three kinds of steel after different temperature tempering the microstructure of tempered martensite lath, and increase with increasing tempering temperature, the part of the martensite lath dissolved, tempering temperature to 675 ℃, can see the martensite lath clear reply. At the same time, a large number of second phase particles precipitate during high temperature tempering. Energy spectrum Figure (F) shows that these dispersed precipitates are alloy carbides. When the tempering temperature rises from 600℃ to 650℃, the precipitate amount of alloy carbides increases significantly, which may be because martensite is decomposed during tempering. The supersaturated C atoms and alloying elements are dissolved from martensite to form carbides. With the increase of tempering temperature, the diffusion rate of solute atoms is accelerated, thus the carbides are precipitated. The red circle pointed by the arrow in Figure (b) ~ (e) is a partial enlarged figure, from which it can be seen more clearly that with the increase of tempering temperature, the morphology of alloy carbide changes from sheet to short rod, and finally occurs spheroidization at 675℃.